Investigation of Electrodes and Electrolytes for Obtaining Amphoteric Decoupled Zn-MnO2 Rechargeable Batteries

Doctoral Thesis

Ramona Zukule, Riga Technical University, Latvia

The Doctoral Thesis is a thematically unified collection of four original research articles and one review paper. The study focuses on improving rechargeable aqueous Zn-MnO2 batteries by investigating the interaction between electrodes and electrolytes and their impact on the voltage. The study develops a pH-gradient, electrolyte concept that enables the extension of the water-splitting voltage window beyond 2 V. Additionally, the stability of the MnO2 cathode was enhanced through Bi3+ and Mo6+ ion doping, and the Zn anode cyclability was improved by laser-induced surface structuring. The results contribute to the development of safer, more sustainable energy storage technologies.

Additional information

Publication type

Defence date

10.12.2025.

Format

Pages

145

Publication date

Published online

Publication language

,

Publisher

RTU Press

Country of Publication

Latvia

Funding source

,